IODIMETRIC TITRATIONS When an analyte that is a reducing agent (like hypo) is titrated directly with a standard iodine solution, the method is called “iodimetry”. involve the potentiometric titration of aqueous iodine with sodium thiosulfate the analyte (a reducing agent) reacts with iodine to produce iodide: iodimetry. Titrations Fajans Preciptation Complexometric. Fact File 1: Introduction to iodometric and iodimetric titrations. Quantitative Classical Chemical Analysis. Titrations.

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With red wines it is difficult to see the equivalence point because their intense red colour makes it difficult to perceive the colour change in the indicator. Sulphur dioxide has several important functions: Some typical kinds of chemical reactions: Iodine in organic solvents, such as diethyl ether and carbon tetrachloridemay be titrated against sodium thiosulfate dissolved in acetone. I will talk, you will listen During the lecture I will ask you some questions and at the end, you will do some tasks to check that you have understood the essential information.

We divide these titrations into two types. Therefore, in this case, only one redox reaction takes place unlike in the case of the Iodometric titration. Introduction to iodometric and iodimetric titrations When a reducing analyte is titrated with iodine the titrantthe method is called iodimetry.

Difference Between Iodometry and Iodimetry

Once sulphur dioxide is added to wine it does not remain free but oxidates in part and in part combines with other molecues:. Istituto Magistrale “Leonardo da Vinci” di Alba. Both involve iodine, but as you will see there are some differences. Firstly, acid-base titrations, secondly complexometric titrations, thirdly precipitation titrations and fourthly redox titrations. Introduction to iodometric and iodimetric titrations Analytical applications: In this case the analyte is an oxidizing agent.


Le lezioni del Corso 1.

The iodine content and thus the active chlorine content can be determined with iodometry. Thus when a diluted but excess amount of standard iodine solution is iodometruc to known volume of sample, the sulfurous acid and sulfites present reduces iodine quantitatively:.

In doing so, it becomes reduced, and is therefore the iodometriv or compund that gain electrons. Then we should carry out another titration with the same mixture to determine the released amount of iodine. As the names Iodometry and Iodimetry suggest, they relate to a process where Iodine is involved.

Available chlorine refers to chlorine liberated by the action of dilute acids on hypochlorite. Then we can titrate the released iodine with another species.

We need to add starch as an indicator, to determine the end point of this reaction. Overview and Key Difference 2. In IodometryIodine gets oxidized first and then reduced by a reducing agent.

The reducing agent used does not necessarily need to be thiosulfate; stannous chloridesulfitessulfidesarsenic IIIand antimony III salts are commonly used alternatives. My presentations Iiodimetric Feedback Log out. Then we can titrate it with a known solution of KI, and we can find the volume consumed. Wikipedia ; burette, source: As mentioned in the definition, this is a direct titration method. Oxidation reduction titration The key difference between iodometry and iodimetry is that we can use Iodometry to quantify oxidizing agentswhereas we can use iodimetry to quantify reducing agents.

Neutralisation titration – part two. To summarise the main information about iodimetric and iodometric titrations: Performing the titration Scales, source: Iodine dissolves in the iodide-containing solution to give iodometrkc ions, which have a dark brown color. Once the bond between the iodine I 2 and the helical chain of beta-amylose is formed it turns an intense blue. Then the produced Iodine is titrated with a reducing agent such as sodium thiosulfate solution.


Now, we are going to look at the redox titrations involving iodine. Iodine forms a deep-blue colour complex with starch and as the Iodine breaks down to Iodide ions, the colour disappears.

The excess arsenic trioxide is then determined by titrating against standard iodine solution using starch iodimftric.


Application of Iodometry In the food industry, iodometry is widely used to determine the concentration of hydroperoxides in any given lipid matrix oils and fats for human consumption. The total sulphur dioxide in the wine sample is determined through direct iodimetric titration using starch as the indicator. A direct titration with only 1 reaction: This is the initial redox reaction. The titration reaction can be represented as:.


The turning point indicates that all the iodine released titrayions been titrated. The technique of Iodometry is commonly used in experiments where the amount of oxidizing agents in a iodometrkc body needs to be quantified.

Licensed under Public Domain via Commons. To drive the reaction to completion, an excess amount of zinc salt can be added to the reaction mixture containing potassium ions, which precipitates the hexacyanoferrate II ion quantitatively:. Introduction to iodometric and iodimetric titrations There are a lot of redox titrations classified according to the titrant used.